Co‐doping Strategy for Developing Perovskite Oxides as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction

Electrocatalysis: Co‐doping Strategy for Developing Perovskite Oxides as Highly Efficient Electrocatalysts for Oxygen Evolution Reaction (Adv. Sci. 2/2016)

Synthesis of perovskite-based porous La(0.75)Sr(0.25)MnO3 nanotubes as a highly efficient electrocatalyst for rechargeable lithium-oxygen batteries.

Rechargeable lithium–oxygen (Li-O2) batteries have recently attracted great attention because they can theoretically store 5–10 times more energy than current lithium-ion batteries, which is essential for clean energy storage, electric vehicles, and other high-energy applications. However, to use Li-O2 batteries for practical applications, numerous scientific and technical challenges need to be...

An aqueous preoxidation method for monolithic perovskite electrocatalysts with enhanced water oxidation performance

Perovskite oxides with poor conductivity call for three-dimensional (3D) conductive scaffolds to demonstrate their superb reactivities for oxygen evolution reaction (OER). However, perovskite formation usually requires high-temperature annealing at 600° to 900°C in air, under which most of the used conductive frameworks (for example, carbon and metal current collectors) are reductive and cannot...

Engineering electrocatalytic activity in nanosized perovskite cobaltite through surface spin-state transition

The activity of electrocatalysts exhibits a strongly dependence on their electronic structures. Specifically, for perovskite oxides, Shao-Horn and co-workers have reported a correlation between the oxygen evolution reaction activity and the eg orbital occupation of transition-metal ions, which provides guidelines for the design of highly active catalysts. Here we demonstrate a facile method to ...

Perovskite Electrocatalysts for the Oxygen Reduction Reaction in Alkaline Media

Oxygen reduction is considered a key reaction for electrochemical energy conversion but slow kinetics hamper application in fuel cells and metal-air batteries. In this review, the prospect of perovskite oxides for the oxygen reduction reaction (ORR) in alkaline media is reviewed with respect to fundamental insight into activity and possible mechanisms. For gaining these insights, special emphas...